A series of cyanide-bridged binuclear complexes
نویسندگان
چکیده
منابع مشابه
Synthesis of Binuclear Monohydroxo Bridged Copper(II) Complexes with 1,10-Phenanthroline and 4,4'-Dimethyl-2,2'-Bipyridine
Tow new compound of type [(chelate)2Cu-OH-Cu(chelate)2] X3.nH2O, where chelate=1,10-phenanthroline; X=Cl¯(n=3.5) and chelate=4,4'-dimethyl-2,2'-bipyridine; (n=5) have been synthesized and their properties investigated. The complexes show room temperature magnetic moment order of 1.0 B.M. per copper atom. The X-band ESR spectrum of powdered sample...
متن کاملsynthesis of binuclear platinum complexes containing biphosphine ligand
هدف از این مطالعه طراحی یک روش کلی برای سنتز یک سری از کمپلکس های دو هسته ای متقارن سیکلومتاله شده پلاتین (ii) بوده که دارای یک لیگاند پل زن(1,2-bis[bis(pentafluoro-phenyl)phosphino]ethane),dfppe, است. از واکنش cis-[pt(r)2(sme2)2]، که در آنr= para-tolyl ، با یک اکی والان از لیگاند benzo[h]quinoline,bhq، در استون محصول [pt(r)(bhq)(sme2)] که در آن r= para-tolyl بدست می آید. همچنین از واکنش 5/0 اک...
synthesis of binuclear monohydroxo bridged copper(ii) complexes with 1,10-phenanthroline and 4,4'-dimethyl-2,2'-bipyridine
tow new compound of type [(chelate)2cu-oh-cu(chelate)2] x3.nh2o, where chelate=1,10-phenanthroline; x=cl¯(n=3.5) and chelate=4,4'-dimethyl-2,2'-bipyridine; (n=5) have been synthesized and their properties investigated. the complexes show room temperature magnetic moment order of 1.0 b.m. per copper atom. the x-band esr spectrum of powdered samples at room temperature shows typical dm=1 transit...
متن کاملA ferromagnetically coupled Fe42 cyanide-bridged nanocage
Self-assembly of artificial nanoscale units into superstructures is a prevalent topic in science. In biomimicry, scientists attempt to develop artificial self-assembled nanoarchitectures. However, despite extensive efforts, the preparation of nanoarchitectures with superior physical properties remains a challenge. For example, one of the major topics in the field of molecular magnetism is the d...
متن کاملElectron spin resonance, magnetic and superoxide dismutase activity of binuclear imidazolate bridged complexes
Electron paramagnet ic resonance, magnet ic suscepti bility and superox ide d ismutase (SOD) activity measurements o f imidazolate bri dged [(Salval)Cu-lm-Cu(Salval)]Na, [(Salval)Cu-lm-Ni (Salval)]Na and [(Salval)Cu-lm-Zn(Sa lva l)1 a complexes, [where salval = salicyledenevalinate, im = imidazolate ion,] are described . Related mononuclear copper(l l) compel xes are also synt hesized . T he p ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Inorganica Chimica Acta
سال: 2009
ISSN: 0020-1693
DOI: 10.1016/j.ica.2009.05.042